There are 2 steps to change a primary domain in Plesk for VPS/ Dedicated Server Hosting
a) Renaming a domain via Plesk
- Go to Domains > example.com > Hosting Settings. 
- In the Domain name field, change the domain name. 
- Apply the changes. - Note: If this is the main domain, subscription name will be also changed.  
b) Renaming a domain via a command-line interface
- Connect to a Plesk server via SSH (Linux) / RDP (Windows Server). 
- Use the 'plesk bin site' utility to rename a domain. In the example below, we are renaming example.com to example.net: - Note: On Windows Server, start a command prompt as an Administrator. - # plesk bin site --update example.com -new_name example.net 
